Self-assembly of tetrareduced corannulene with mixed Li–Rb clusters: dynamic transformations, unique structures and record7Li NMR shifts
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چکیده
منابع مشابه
Self-assembly of tetrareduced corannulene with mixed Li-Rb clusters: dynamic transformations, unique structures and record 7Li NMR shifts.
Self-assembly processes of the highly reduced bowl-shaped corannulene generated by the chemical reduction with a binary combination of alkali metals, namely Li-Rb, have been investigated by variable-temperature 1H and 7Li NMR spectroscopy. The formation of several unique mixed metal sandwich products based on tetrareduced corannulene, C20H104- (14-), has been revealed followed by investigation ...
متن کاملSelf-assembly of tetrareduced corannulene with mixed Li–Rb clusters: dynamic transformations, unique structures and record 7Li NMR shifts† †Electronic supplementary information (ESI) available: Experimental and synthetic procedures, characterization data, computational details, and crystallographic methods employed in this work are given. CCDC 1032187 and 1032188. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03485f Click here for additional data file. Click here for additional data file.
Department of Chemistry, University at Alba NY 12222, USA. E-mail: mpetrukhina@alba Department of Chemistry, University of Wis Department of Biological and Chemical S Chicago, IL 60616, USA † Electronic supplementary information synthetic procedures, characterization crystallographic methods employed in th 1032188. For ESI and crystallographic dat DOI: 10.1039/c4sc03485f Cite this: Chem. Sci., ...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c4sc03485f